CA2071745C - Particulate detergent composition or component - Google Patents
Particulate detergent composition or componentInfo
- Publication number
- CA2071745C CA2071745C CA002071745A CA2071745A CA2071745C CA 2071745 C CA2071745 C CA 2071745C CA 002071745 A CA002071745 A CA 002071745A CA 2071745 A CA2071745 A CA 2071745A CA 2071745 C CA2071745 C CA 2071745C
- Authority
- CA
- Canada
- Prior art keywords
- component
- detergent composition
- liquid
- zeolite map
- ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 67
- 239000003599 detergent Substances 0.000 title claims abstract description 61
- 239000010457 zeolite Substances 0.000 claims abstract description 106
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 101
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 101
- 239000007788 liquid Substances 0.000 claims abstract description 52
- 239000004615 ingredient Substances 0.000 claims abstract description 51
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 38
- 239000012876 carrier material Substances 0.000 claims abstract description 29
- 239000004411 aluminium Substances 0.000 claims abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims description 52
- 239000002245 particle Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- -1 secondary alcohol sulphate Chemical class 0.000 claims description 9
- 239000008187 granular material Substances 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 5
- 239000002243 precursor Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 238000009826 distribution Methods 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 125000000075 primary alcohol group Chemical group 0.000 claims description 2
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 18
- 238000000034 method Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 13
- 239000002585 base Substances 0.000 description 12
- 239000004094 surface-active agent Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 238000005469 granulation Methods 0.000 description 7
- 230000003179 granulation Effects 0.000 description 7
- 239000003921 oil Substances 0.000 description 6
- 229920006243 acrylic copolymer Polymers 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 230000000740 bleeding effect Effects 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 5
- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 102000005701 Calcium-Binding Proteins Human genes 0.000 description 3
- 108010045403 Calcium-Binding Proteins Proteins 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- GBFLZEXEOZUWRN-VKHMYHEASA-N S-carboxymethyl-L-cysteine Chemical compound OC(=O)[C@@H](N)CSCC(O)=O GBFLZEXEOZUWRN-VKHMYHEASA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000007580 dry-mixing Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 230000003185 calcium uptake Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0034—Fixed on a solid conventional detergent ingredient
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB919113675A GB9113675D0 (en) | 1991-06-25 | 1991-06-25 | Particulate detergent composition or component |
| GB9113675.4 | 1991-06-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2071745A1 CA2071745A1 (en) | 1992-12-26 |
| CA2071745C true CA2071745C (en) | 1998-10-27 |
Family
ID=10697275
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002071745A Expired - Lifetime CA2071745C (en) | 1991-06-25 | 1992-06-19 | Particulate detergent composition or component |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US5518649A (en]) |
| EP (1) | EP0521635B1 (en]) |
| JP (1) | JPH0739594B2 (en]) |
| KR (1) | KR960001011B1 (en]) |
| AU (1) | AU660466B2 (en]) |
| BR (1) | BR9202394A (en]) |
| CA (1) | CA2071745C (en]) |
| CZ (1) | CZ280366B6 (en]) |
| DE (1) | DE69232364T2 (en]) |
| ES (1) | ES2170749T3 (en]) |
| GB (1) | GB9113675D0 (en]) |
| HU (1) | HU216715B (en]) |
| IN (1) | IN176371B (en]) |
| MY (1) | MY106931A (en]) |
| NZ (1) | NZ243249A (en]) |
| PH (1) | PH31613A (en]) |
| PL (1) | PL174152B1 (en]) |
| SA (1) | SA92130031B1 (en]) |
| SK (1) | SK278646B6 (en]) |
| ZA (1) | ZA924708B (en]) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU4326193A (en) * | 1992-06-25 | 1994-01-24 | Unilever Plc | Machine dishwashing composition |
| GB9216386D0 (en) * | 1992-07-31 | 1992-09-16 | Unilever Plc | Use of aluminosilicates of the zeolite p type as low temperature calcium binders |
| GB9313878D0 (en) * | 1993-07-05 | 1993-08-18 | Unilever Plc | Detergent composition or component containing anionic surfactant and process for its preparation |
| GB9324129D0 (en) * | 1993-11-24 | 1994-01-12 | Unilever Plc | Detergent compositions and process for preparing them |
| GB2288187A (en) * | 1994-03-31 | 1995-10-11 | Procter & Gamble | Detergent composition |
| GB2288813A (en) * | 1994-04-28 | 1995-11-01 | Procter & Gamble | Granular Detergent Composition |
| GB2294269A (en) * | 1994-10-21 | 1996-04-24 | Procter & Gamble | Detergent composition |
| GB9500536D0 (en) * | 1995-01-11 | 1995-03-01 | Unilever Plc | Particles containing perfume |
| US5925614A (en) * | 1995-04-27 | 1999-07-20 | The Procter & Gamble Company | Process for producing granular detergent components or compositions |
| DE69506842T2 (de) * | 1995-04-27 | 1999-08-05 | Procter & Gamble | Verfahren zur Herstellung von granularen Waschmittelkomponenten oder Waschmittelzusammensetzungen |
| WO1996034082A1 (en) * | 1995-04-27 | 1996-10-31 | The Procter & Gamble Company | Process for producing granular detergent components or compositions |
| GB9519587D0 (en) * | 1995-09-26 | 1995-11-29 | Procter & Gamble | Detergent compositions |
| GB9605534D0 (en) * | 1996-03-15 | 1996-05-15 | Unilever Plc | Detergent compositions |
| CN1256710A (zh) * | 1997-03-20 | 2000-06-14 | 普罗格特-甘布尔公司 | 具有多重表面涂布物的洗衣添加剂颗粒 |
| DE19721885A1 (de) † | 1997-05-26 | 1998-12-03 | Henkel Kgaa | Verfahren zur Herstellung kationtensidhaltiger Granulate |
| GB9711356D0 (en) | 1997-05-30 | 1997-07-30 | Unilever Plc | Particulate detergent composition |
| GB9711350D0 (en) * | 1997-05-30 | 1997-07-30 | Unilever Plc | Granular detergent compositions and their production |
| GB9711359D0 (en) | 1997-05-30 | 1997-07-30 | Unilever Plc | Detergent powder composition |
| ID29296A (id) | 1997-05-30 | 2001-08-16 | Unilever Nv | Komposisi deterjen butiran lembut yang bebas mengalir |
| DE19855676A1 (de) * | 1998-12-02 | 2000-06-08 | Henkel Kgaa | Wasch- und Reinigungsmitteladditiv und Verfahren zu dessen Herstellung |
| GB9913546D0 (en) | 1999-06-10 | 1999-08-11 | Unilever Plc | Granular detergent component containing zeolite map and laundry detergent compositions containing it |
| MY133398A (en) * | 1999-07-09 | 2007-11-30 | Colgate Palmolive Co | Fabric cleaning composition containing zeolite |
| US6204239B1 (en) * | 1999-11-24 | 2001-03-20 | Colgate-Palmolive, Inc. | Fabric cleaning composition containing zeolite |
| DE19961687A1 (de) * | 1999-12-21 | 2001-07-05 | Henkel Kgaa | Wirkstoffkombination zur Einarbeitung in Wasch- und Reinigungsmittel |
| EP1215277B2 (en) † | 2000-12-18 | 2009-11-25 | Kao Corporation | Base particles and detergent particles |
| GB0111862D0 (en) | 2001-05-15 | 2001-07-04 | Unilever Plc | Granular composition |
| GB0111863D0 (en) * | 2001-05-15 | 2001-07-04 | Unilever Plc | Granular composition |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3112176A (en) * | 1961-10-04 | 1963-11-26 | Minerals & Chem Philipp Corp | Base-exchange zeolite and method for making the same |
| US3769222A (en) * | 1971-02-09 | 1973-10-30 | Colgate Palmolive Co | Free flowing nonionic surfactants |
| AT373276B (de) * | 1974-02-25 | 1984-01-10 | Henkel Kgaa | Nichtionische tenside enthaltende schuettfaehige wasch- und reinigungsmittel |
| DE2620293A1 (de) * | 1976-05-07 | 1977-11-17 | Degussa | Verfahren zur herstellung von feinteiligem, kationenaustauschendem molekularsieb |
| US4265777A (en) * | 1980-04-17 | 1981-05-05 | The Procter & Gamble Company | Detergent compositions containing an aluminosilicate detergency builder and an unsaturated fatty acid soap |
| DE3169193D1 (en) * | 1980-10-29 | 1985-04-11 | Procter & Gamble | Aluminosilicate-agglomerates and detergent compositions containing them |
| GB8329880D0 (en) * | 1983-11-09 | 1983-12-14 | Unilever Plc | Particulate adjuncts |
| DE3424987A1 (de) * | 1984-07-06 | 1986-02-06 | Unilever N.V., Rotterdam | Verfahren zur herstellung eines pulverfoermigen waschmittels mit erhoehtem schuettgewicht |
| DE3434854A1 (de) * | 1984-09-22 | 1986-04-03 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur herstellung einer koernigen, freifliessenden waschmittelkomponente |
| DE3444960A1 (de) * | 1984-12-10 | 1986-06-12 | Henkel KGaA, 4000 Düsseldorf | Koerniges adsorptionsmittel |
| DE3444959A1 (de) * | 1984-12-10 | 1986-06-12 | Henkel KGaA, 4000 Düsseldorf | Teppichreinigungsmittel |
| DE3514364A1 (de) * | 1985-04-20 | 1986-10-23 | Henkel KGaA, 4000 Düsseldorf | Koerniges waschmittel mit verbessertem reinigungsvermoegen |
| EP0227720A1 (de) * | 1985-06-22 | 1987-07-08 | Henkel Kommanditgesellschaft auf Aktien | Waschmittel für niedere waschtemperaturen |
| GB8825783D0 (en) * | 1988-11-03 | 1988-12-07 | Unilever Plc | Novel aluminosilicates & detergent compositions containing them |
| CA2001927C (en) * | 1988-11-03 | 1999-12-21 | Graham Thomas Brown | Aluminosilicates and detergent compositions |
| EP0448297A1 (en) * | 1990-03-19 | 1991-09-25 | Unilever Plc | Detergent compositions |
| GB9006171D0 (en) * | 1990-03-19 | 1990-05-16 | Unilever Plc | Detergent compositions |
| GB9113674D0 (en) * | 1991-06-25 | 1991-08-14 | Unilever Plc | Detergent compositions |
| CZ280593B6 (cs) * | 1992-01-17 | 1996-02-14 | Unilever Nv | Částicové detergenční směsi |
| SK278834B6 (sk) * | 1992-01-17 | 1998-03-04 | Unilever Nv | Časticová bieliaca detergentná zmes |
-
1991
- 1991-06-25 GB GB919113675A patent/GB9113675D0/en active Pending
-
1992
- 1992-06-12 MY MYPI92001197A patent/MY106931A/en unknown
- 1992-06-18 EP EP92305590A patent/EP0521635B1/en not_active Expired - Lifetime
- 1992-06-18 ES ES92305590T patent/ES2170749T3/es not_active Expired - Lifetime
- 1992-06-18 DE DE69232364T patent/DE69232364T2/de not_active Expired - Lifetime
- 1992-06-19 CA CA002071745A patent/CA2071745C/en not_active Expired - Lifetime
- 1992-06-22 NZ NZ243249A patent/NZ243249A/en not_active IP Right Cessation
- 1992-06-23 PH PH44550A patent/PH31613A/en unknown
- 1992-06-24 IN IN200BO1992 patent/IN176371B/en unknown
- 1992-06-24 AU AU18503/92A patent/AU660466B2/en not_active Expired
- 1992-06-24 SK SK1951-92A patent/SK278646B6/sk not_active IP Right Cessation
- 1992-06-24 PL PL92295004A patent/PL174152B1/pl unknown
- 1992-06-24 BR BR929202394A patent/BR9202394A/pt not_active IP Right Cessation
- 1992-06-24 KR KR1019920010995A patent/KR960001011B1/ko not_active Expired - Fee Related
- 1992-06-24 CZ CS921951A patent/CZ280366B6/cs not_active IP Right Cessation
- 1992-06-24 HU HU9202101A patent/HU216715B/hu unknown
- 1992-06-25 ZA ZA924708A patent/ZA924708B/xx unknown
- 1992-06-25 JP JP4167958A patent/JPH0739594B2/ja not_active Expired - Fee Related
- 1992-07-27 SA SA92130031A patent/SA92130031B1/ar unknown
-
1995
- 1995-08-11 US US08/514,475 patent/US5518649A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CZ195192A3 (en) | 1994-04-13 |
| KR930000668A (ko) | 1993-01-15 |
| CA2071745A1 (en) | 1992-12-26 |
| AU1850392A (en) | 1993-01-07 |
| EP0521635B1 (en) | 2002-01-23 |
| CZ280366B6 (cs) | 1996-01-17 |
| HUT61808A (en) | 1993-03-01 |
| SA92130031B1 (ar) | 2004-08-14 |
| BR9202394A (pt) | 1993-01-26 |
| ZA924708B (en) | 1993-12-27 |
| PL295004A1 (en) | 1993-03-08 |
| DE69232364D1 (de) | 2002-03-14 |
| GB9113675D0 (en) | 1991-08-14 |
| ES2170749T3 (es) | 2002-08-16 |
| MY106931A (en) | 1995-08-30 |
| PL174152B1 (pl) | 1998-06-30 |
| HU216715B (hu) | 1999-08-30 |
| HK1014261A1 (en) | 1999-09-24 |
| AU660466B2 (en) | 1995-06-29 |
| JPH0641596A (ja) | 1994-02-15 |
| KR960001011B1 (ko) | 1996-01-17 |
| SK195192A3 (en) | 1994-08-10 |
| SK278646B6 (en) | 1997-12-10 |
| NZ243249A (en) | 1994-11-25 |
| JPH0739594B2 (ja) | 1995-05-01 |
| IN176371B (en]) | 1996-05-18 |
| US5518649A (en) | 1996-05-21 |
| HU9202101D0 (en) | 1992-10-28 |
| EP0521635A1 (en) | 1993-01-07 |
| PH31613A (en) | 1999-01-12 |
| DE69232364T2 (de) | 2002-07-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |